{N,N-Bis[bis­(2,2,2-tri­fluoro­eth­oxy)phosphan­yl]methyl­amine-κ2 P,P′}bis­(η5-cyclo­penta­dien­yl)titanium(II)

نویسندگان

  • Martin Haehnel
  • Sven Hansen
  • Anke Spannenberg
  • Torsten Beweries
چکیده

The title compound, [Ti(C5H5)2(C9H11F12NO4P2)], is a four-membered titanacycle obtained from the reaction of Cp2Ti(η(2)-Me3SiC2SiMe3) and CH3N[P(OCH2CF3)2]2 {N,N-bis-[bis-(tri-fluoro-eth-oxy)phosphan-yl]methyl-amine, tfepma}. The Ti(II) atom is coordinated by two cyclo-penta-dienyl (Cp) ligands and the chelating tfepma ligand in a strongly distorted tetra-hedral geometry. The mol-ecule is located on a mirror plane.

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عنوان ژورنال:

دوره 69  شماره 

صفحات  -

تاریخ انتشار 2013